In Luke 22:16-20 was the drink Jesus blessed wine because grapes had not ripened at that time and the preservation of grape juice was unknown then?

The preservation of grape juice or the prevention of its fermentation has been known since ancient times.  The process was described by the Roman statesman Cato the Younger (95-46 B.C.) in De Agri Cultura CXX: “If you wish to have [grape juice] all year, put [grape juice] in an amphora and seal the cork with pitch; sink it in a fishpond.  After thirty days take it out.  It will be [grape juice] for a whole year”. 

Grape juice was also available year round by the rehydration of raisins.